PUBLISHED WORK

TOC_graphic_yy.tif

46. Efficient C-H amination catalysis using nickel-dipyrrin complexes

Dong, Y.; Clarke, R. M.; Porter, G. P.; Betley, T. A. J. Am. Chem. Soc.2020, 142, 25, 10996-11005

fortyfour.jpg

44. Synthesis and electronic structure studies of a Cr-imido redox series

Dong, Y.; Clarke, R. M.; Zheng, S-L.; Betley, T. A. Chem. Commun.2020, 56, 3163-3166

45. C–H Amination Mediated by Cobalt Organoazide Adducts and the Corresponding Cobalt Nitrenoid Intermediates

Baek, Y.; Das, A.; Zheng, S.-L.; Reibenspies, J. H.; Powers, D.C.; Betley, T.A. 

J. Am. Chem. Soc.2020, 142, 25, 11232-11243

fortyone.jpeg

41. The Myth of d8 Copper(III)

DiMucci, I. M.; Lukens, J. T.; Chatterjee, S.; Carsch, K. M.; Titus, C. J.; Lee, S. J.; Nordlund, D.; Betley, T.A.; MacMillan, S. N.; Lancaster, K. M.; 

J. Am. Chem. Soc.2019, 141, 46, 18508-18520

fourtytwo.jpg

42. Synthesis, Characterization and C–H Amination Reactivity of Nickel Iminyl Complexes

Dong, Y.; Lukens, J.; Clarke, R. M.; Zheng, S-L.; Lancaster, K.;  Betley, T. A. Chem. Sci.2020, 11, 1260-1268

43. Electronic Structures and Reactivity Profiles of Aryl Nitrenoid-Bridged Dicopper Complexes

Carsch, K. M.; Lukens, J. T.; DiMucci, I. M.; Iovan, D. A.; Zheng, S.-L.; Lancaster, K. M.; Betley, T.A. 

J. Am. Chem. Soc.2020142, 5, 2264-2276

fourty.jpg

40. Direct Manipulation of Metal Imido Geometry: Key Principles to Enhance C–H Amination Efficacy

Baek, Y.; Hennessy, E. T.; Betley, T.A. J. Am. Chem. Soc.2019141, 16944

39. Synthesis of a Copper-Supported Triplet Nitrene Complex Pertinent to Copper-Catalyzed Amination

Carsch, K. M.; DiMucci, I. M.; Iovan, D. A.; Li, A.; Zheng, S.-L.; Titus, C. J.; Lee, S. J.; Irwin, K. D.; Nordlund, D.; Lancaster, K. M.; Betley, T.A. Science., 2019365, 1138

thirtyeight.jpg

38. Exposing the Inadequacy of Redox Formalisms by Resolving Redox Inequivalence within Isovalent Clusters.

Batholomew, A. K.; Teesdale, J. J.; Hernández Sánchez, R.; Malbrecht, B. J.; Juda, C. E.; Ménard , G.; Bu, W.; Iovan, D. A.; Mikhailine, A. A.; Zheng, S.-L.; Sarangi, R.; Wang, S. G.; Chen, Y.-S.; Betley, T.A. Proc. Natl. Acad. Sci., 2019116, 15836

thirtyseven.jpg

37. Diiron Oxo Reactivity In a Weak-Field Environment.

Johnson, E. J.; Kleinlein, C.; Musgrave, R. A.; Betley, T. A. Chem. Sci.201910, 63046

thirtysix.jpg

36. Catalytic C–H Amination Mediated by Dipyrrin Cobalt Imidos.

Baek, Y.; Betley, T. A. J. Am. Chem. Soc., 2019141, 7797

thirtyfive.jpg

 35. Ligand‐Based Control of Single‐Site vs. Multi‐Site Reactivity by a Trichromium Cluster.

Bartholomew, A. K.; Juda, C. E.; Nessralla, J. N.; Lin, B.; Wang, S. G.; Chen, Y.; Betley, T. A. Angew. Chem. Int. Ed., 201958, 5687

thirtyfour.jpg

34. Thermally Persistent High-Spin Ground States in Octahedral Iron Clusters.

Hernández Sánchez, R.; Betley, T. A. J. Am. Chem. Soc., 2018, 140, 16792

thirtythree.jpg

33. Diastereoselective C–H Bond Amination for Disubstituted Pyrrolidines.

Iovan, D. A.; Wilding, M. J. T.; Baek, Y.; Hennessy, E. T.; Betley, T. A. Angew. Chem. Int. Ed.201756, 15599

thirtytwo.jpg

32. Direct Comparison of C–H Bond Amination Efficacy through Manipulation of Nitrogen-Valence Centered Redox: Imido versus Iminyl.

Wilding, M. J. T.; Iovan, D. A.; Wrobel, A. T.; Lukens, J. T.; MacMillan, S. N.; Lancaster, K. M.; Betley, T. A. J. Am. Chem. Soc., 2017139, 14757

thirtyone.jpg

31. Reactivity of a stable copper-dioxygen complex.

Iovan, D. A.; Wrobel, A. T.; McClelland, A. A.; Scharf, A. B.; Edouard, G. A.; Betley, T. A. Chem. Commun., 201753, 10306.

thirty.jpg

30. High spin iron imido complexes competent for C-H bond amination

Wilding, M. J. T.; Iovan, D. A.; Betley, T. A. J. Am. Chem. Soc., 2017139, 12043.

twentynine.jpg

29. C-H Activation from Iron(II)-Nitroxido Complexes

Kleinlein, C.; Bendelsmith, A. J.; Zheng, S.-L.; Betley, T. A. Angew. Chem. Int. Ed.201756, 1.

twentyeight.jpg

28. Ground State and Excited State Tuning in Ferric Dipyrrin Complexes Promoted by Ancillary Ligand Exchange

Kleinlein, C.; Zheng, S.-L.; Betley, T. A. Inorg. Chem., 201756, 5892.

twentyseven.jpg

27. Characterization of Iron–Imido Species Relevant for N–Group Transfer Chemistry

Iovan, D. A.; Betley, T. A. J. Am Chem. Soc., 2016138, 1983.

twentysix.jpg

26. Maximizing Electron Exchange in a [Fe3] Cluster

Hernández Sánchez, R.; Bartholomew, A. K.; Powers, T. M.; Ménard , G.; Betley, T. A. J. Am. Chem. Soc., 2016138, 2235.

twentyfive.jpg

25. Meta-Atom Behavior in Clusters Revealing Large Spin Ground States

Hernández Sánchez, R.; Betley, T. A. J. Am. Chem. Soc., 2015, 137, 13949

twentyfour.jpg

24. Ligand Field Strength Mediates Electron Delocalization in Octahedral [(HL)2Fe6(L')m]n+ Clusters

Hernández Sánchez, R.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc.2015 , 137, 11126.

twentythree.jpg

23. Synthesis of Well-Defined Bicapped Octahedral Iron Clusters [(trenL)2Fe8(PMe2Ph)2]n (n=0, −1)

Hernández Sánchez, R.; Willis, A. M.; Zheng, S.-L.; Betley, T. A. Angew. Chem. Int. Ed., 2015, 54, 12009.

twentytwo.jpg

22. Iron-mediated Intermolecular N-Group Transfer Chemistry with Olefinic Substrates

Hennessy, E. T.; Liu, R. Y.; Iovan, D. A.; Duncan, R. A.; Betley, T. A. Chem. Sci., 2014, 5, 1526.

twentyone.jpg

21. Multiple, Disparate Redox Pathways Exhibited by a Tris(pyrrolido)ethane Iron Complex

Sazama, G. T.; Betley, T. A. Inorg. Chem., 201453, 269.

twenty.jpg

20. Synthesis of Open-Shell, Bimetallic Mn/Fe Trinuclear Clusters

Powers, T. M; Gu, N. X.; Fout, A. R.; Baldwin, A. M.; Hernández Sánchez, R.; Alfonso, D. M.; Chen, Y.; Zheng, S.-L.; Betley, T. A. J. Am. Chem.  Soc., 2013135, 14448.

nineteen.jpg

19. Testing the Polynuclear Hypothesis: Multielectron Reduction of Small Molecules by Triiron Reaction Sites

Powers, T. M.; Betley, T. A. J. Am. Chem. Soc., 2013135, 12289.

eighteen.jpg

18. Complex N-Heterocycle Synthesis via Iron-Catalyzed, Direct C-H Bond Amination

Hennessy, E. T.; Betley, T. A. Science2013340, 591.

seventeen.jpg

17. Metal Atom Lability in Polynuclear Complexes

Eames, E. V.; Hernández Sánchez, R.; Betley, T. A. Inorg. Chem2013, 52, 5006.

sixteen.jpg

16. Co(III) Imidos Exhibiting Spin Crossover and C–H Bond Activation

King, E. R.; Sazama, G. T.; Betley, T. A. J. Am. Chem. Soc., 2012134, 17858.

fifteen.jpg

15. Trigonal Mn3 and Co3 Clusters Supported by Weak-Field Ligands: A Structural, Spectroscopic, Magnetic, and Computational Investigation into the Correlation of Molecular and Electronic Structure

Fout, A. R.; Xiao, D. J.; Zhao, Q.; Harris, T. D.; King, E. R.; Eames, E. V.; Zheng, S.-L.; Betley, T. A. Inorg. Chem., 2012, 19, 10290.

fourteen.jpg

14. Site-Isolated Redox Reactivity in a Trinuclear Iron Complex

Eames, E. V.; Betley, T. A. Inorg. Chem., 2012, 19, 10274.

thirteen.jpg

13. Modulation of magnetic behavior via ligand-field effects in the trigonal clusters (PhL)Fe3L*3 (L* = thf, py, PMe2Ph)

Eames, E. V.; Harris, T. D.; Betley, T. A. Chem. Sci.2012, 3, 407.

twelve.jpg

12. Oxidative Atom-Transfer to a Trimanganese Complex To Form Mn6(μ6-E) (E = O, N) Clusters Featuring Interstitial Oxide and Nitride Functionalities

Fout, A. R.; Zhao, Q.; Xiao, D. J.; Betley, T. A. J. Am. Chem. Soc., 2011, 133, 16750.

eleven.jpg

11. Multi-Site Reactivity: Reduction of Six Equivalents of Nitrite To Give an Fe6(NO)6 Cluster with a Dramatically Expanded Octahedral Core

Harris, T. D.; Betley, T. A. J. Am. Chem. Soc., 2011, 133, 13852.

ten.jpg

10. Reductive Coupling of CO Templated by Iron Bound to the Tris(pyrrolide)ethane Scaffold

Sazama, G.T.; Betley, T. A. Organometallics2011, 30, 4315.

nine.jpg

9. Electronic Perturbations of Iron Dipyrrinato Complexes via Ligand β-Halogenation and meso-Fluoroarylation

Scharf, A. B.; Betley, T. A. Inorg. Chem., 2011, 50, 6837.

eight.jpg

8. Expanded redox accessibility via ligand substitution in an octahedral Fe6Br6 cluster

Harris, T. D.; Hernandez Sanchez, R.; Betley, T. A. Chem. Commun., 2011, 47, 6344.

seven.jpg

7. [(HL)2Fe6(NCMe)m]n+ (m = 0, 2, 4, 6; n = −1, 0, 1, 2, 3, 4, 6): An Electron-Transfer Series Featuring Octahedral Fe6 Clusters Supported by a Hexaamide Ligand Platform

Zhao, Q.; Harris, T. D.; Betley, T. A. J. Am. Chem. Soc., 2011, 133, 8293.

six.jpg

6. Catalytic C-H Bond Amination from High-Spin Iron Imido Complexes

King, E. R.; Hennessy, E. T.; Betley, T. A. J. Am. Chem. Soc., 2011, 133, 4917.

five.jpg

5. Oxidative Group Transfer to a Triiron Complex to Form a Nucleophilic μ3-Nitride, [Fe3(μ3-N)]−

Powers, T. M.; Fout, A. R.; Zheng, S.-L.; Betley, T. A. J. Am. Chem. Soc., 2011, 133, 3336.

four.jpg

4. Synthesis and Redox Properties of Triiron Complexes Featuring Strong Fe–Fe Interactions

Zhao, Q.; Betley, T. A. Betley. Angew. Chem. Int. Ed., 2011, 50, 709.

three.jpg

3. Ligand-Centered Redox Activity: Redox Properties of 3d Transition Metal Ions Ligated by the Weak-Field Tris(pyrrolyl)ethane Trianion

Sazama, G. T.; Betley, T. A. Inorg. Chem., 2010, 49, 2512.

two.jpg

2. Unusual Electronic Structure of First Row Transition Metal Complexes Featuring Redox-Active Dipyrromethane Ligands

King, E. R.; Betley, T. A. J. Am. Chem. Soc., 2009, 131, 14374.

one.jpg

1. C−H Bond Amination from a Ferrous Dipyrromethene Complex

King, E. R.; Betley, T. A. Inorg. Chem., 2009, 48, 2361.

HarvardChem_edited.png